Drain and reserve juice from canned pineapple.
Place pork chops in baking dish that is lightly sprayed with cooking spray.
Mix 3 tablespoons of the reserved pineapple juice with brown sugar and nutmeg.
Spoon half of the mixture over the pork chops.
Top with pineapple slices and spoon remaining mixture over pineapple.
Cover and bake 30 minutes at 350 degrees.
Uncover and bake 20 minutes longer, spoon sauce over chops occasionally.